2005年第27卷第3期化学与黏合CHEMISTRYANDADHESION#165#耐张高智1,温胶黏崔卫民3454900剂邢景春2,(1.黑龙江省石油化学研究院,黑龙江哈尔滨150040;2.黑龙江黑龙制药有限公司,黑龙江哈尔滨150086;3.河南利诺生化有限责任公司,河南安阳摘要:耐高温胶黏剂的研究开始于20世纪50年代后期,目的是满足航空和电子工业的需要。至今已报道过许多种耐高温胶黏剂,其中一部分已用于工业生产。这类胶黏剂应用广泛,其中有刹车系统的粘接、高速飞机的油箱密封、高速飞机和航天飞机的结构粘接。未来一段时间,市场需求将迅速增加。本文讨论了几类可以用来配制耐高温胶黏剂的聚合物,其中有聚苯并噻唑、聚酰亚胺、聚喹中图分类号:TQ43714啉及聚硅氧烷。文献标识码:A文章编号:1001-0017(200503-0165-04关键词:胶黏剂;高温;耐热High-temperatureResistanceAdhesivesZHANGZhi1,XINGJing-chun2andCUIWei-min3(1.HeilongjiangInstituteofPetrochemistry,Harbin150040,China;2.HeilongjiangHeilongPharmaceuticalCorporation,Harbin150069,China;3.HenanLinuoBiochem.Co.Ltd,Anyang454900,ChinaAbstract:Studyonhigh-temperatureresistanceadhesivesareinitiatedinthelate1950sprimarilytomeettheneedsofaerospaceandelectronicsindustry.Sincethen,manydifferentheat-resistantadhesiveshavebeenreported,severalofwhicharenowcommerciallyavailable.Theseadhesivesareusedinmanydiverseapplicationssuchasbinderinbrakesystems,sealantsforfueltanksofhigh-speedaircrafts,structuraladhesioninhigh-speedaircraftsandspacevehicles.Thismarketisexpectedtoincreaserapidlyintherecentyears.Themajorclassesofpolymerdevelopedashigh-temperatureresistanceadhesivediscussedinthispaperarepolybenzimidazoles,polyimides,polyquinoxalinesandpolyorganosiloxanes.Keywords:adhesives;high-temperatureresistance;heat-resistant收稿日期:2004-05-18作者简介:张智(1971-,女,哈尔滨市人,助理研究员,从事石油化工及高分子材料方面的科技信息研究工作。[24][25]李文峰,辛文利,吕玲.直接甲醇燃料电池MEA材料的研究及制作进展[J].材料导报,2001,15(3:54~56.符显珠,李俊,卢成慧,等.直接甲醇燃料电池质子膜研究进展[J].化学进展,2004,16(1:77~82.吴洪,王宇新,王世昌.聚乙烯醇膜的阻醇及导电性能(Ò戊二醛交联聚乙烯醇膜[J].高分子材料科学与工程,2003,19(5131~133.[31][32]陈羚,程璇,彭程,等.新型燃料电池用质子交换膜研究进展[J].材料科学与工程,2003,21(5:738~739.HONMAI,HIRAKAWAS,YAMADAK.Synthesisoforganicnanocompositesprotonicconductingmembranethroughsol-gelprocess[J].SolidStateIonics,1999,118:29~36.[26][33][34]何雨石,徐艳辉,庄铭军,等.直接甲醇燃料电池中反应及传递的模型化[J].电源技术,2002,26(4:326~331.ZAIDISM,MIKHAILENKOSDl.Protonconductingcompositemembranesfrompolyetheretherketoneandheteropolyacidsforfuelcellapplications[J].Member.Sci.,2000,173:17[27]LAURENTM,JORGM.Plasma-polymerisedelectrolytemembraneforminiaturiseddirectmethanolfuelcell[J].MembraneTechol.,1999,115:5~9.[28]POLTARZEWSKIZ.Novelprotonconductingcompositeelectrolyteforapplicationinmethanolfuelcell[J].SolidStateIonics.,1999,119:301~304.[35][36]李磊,许莉,王宇新1磺化聚醚醚酮的制备及其阻醇和质子导电性能[J].高分子学报,2003,(3:452~454.李磊,许莉,王宇新.磺化酚酞型聚醚砜膜的制备及其阻醇和质子导电性能[J].高分子学报,2003,(4:465~467.[29]WAINRIGHTJS,WANGJT,WENGD,etal.Acid-dopedPolybenzimidazoles:Anewpolymerelectrolyte[J].ElectrochemSoc.,1995,142(7:L121~123.[37]CARRETTAN,TRICOLIV,PICCHIONIF.Ionomericmembranesbasedonpartiallysulfonatedpoly(styrene:Synthesis,protonconductionandmethanolpermeation[J].Member.Sci.,2000,166(2:189~197.[30]WANGJT,WAINRIGHTJS,SAVINELLRF,etal.Directmethanolfuelcellusingacid-dopedpolybenzimidazoleaspolymerelectrolyte[J].Appl.Electrochem,1996,26:751~756.
